Inelastic scattering and satellite fine structure in the high-resolution uv photoelectron spectrum of CS2
| Autor: | Ingrid Reineck, Karl Erik Norell, C. Nohre, Hans Veenhuizen, Björn Wannberg, R. Maripuu, Lars Mattsson, Kai Siegbahn, Leif Karlsson |
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| Rok vydání: | 1984 |
| Předmět: |
Radiation
Valence (chemistry) Photoemission spectroscopy Chemistry Triatomic molecule Spin–orbit interaction Inelastic scattering Condensed Matter Physics Atomic and Molecular Physics and Optics Spectral line Electronic Optical and Magnetic Materials Physical and Theoretical Chemistry Atomic physics Ionization energy Spectroscopy |
| Zdroj: | Journal of Electron Spectroscopy and Related Phenomena. 34:235-252 |
| ISSN: | 0368-2048 |
| Popis: | The outer valence region in CS 2 has been studied by high-resolution UV photpelectron Spectroscopy. The spectra reveal detailed vibrational structure in the X $ 2 Π g , A $ 2 Π u , B $ 2 Σ + u and C $ 2 Σ + g bands. Some of the fine-structure peaks in the X , B $ and C $ bands are shown to be pressure-dependent. The reason for the pressure dependence is assumed to be inelastic scattering of electrons emitted in the adiabatic transitions. It is established that the two CI satellite bands present in the He(I)-excited spectrum contain vibrational structure. |
| Databáze: | OpenAIRE |
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