Influence of Pressure on Chemical Equilibria in Aqueous Systems - with Particular Reference to Seawater

Autor:	Stuart H. Laurie, Robert H. Byrne
Rok vydání:	1999
Předmět:	Work (thermodynamics) Aqueous solution Chemistry General Chemical Engineering High pressure Environmental chemistry Thermodynamics Context (language use) Seawater General Chemistry Dissolution Acid dissociation constant
Zdroj:	Pure and Applied Chemistry. 71:871-890
ISSN:	1365-3075 0033-4545
DOI:	10.1351/pac199971050871
Popis:	Synopsis: The influence of pressure on chemical equilibria in aqueous solutions and the parameters that influence such equilibria are reviewed in this work. Particular emphasis is given to equilibria in seawater, including mineral dissolution, weak acid dissociation and metal ion complexation. Intended perspectives include the capabilities of predictive models to describe chemical equilibria in low temperature geochemical systems and the extent to which predictive models are constrained by direct observations. In context of the importance of pressure as a key variable controlling the pathways and fate of environmental chemicals, a need for further direct observations of chemical equilibria at high pressure, under conditions which are often challenging to the experimentalist, is evident.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e1cc40cfbb1157391654df6f142a6c34 https://doi.org/10.1351/pac199971050871 Zobrazit plný text záznamu