Comparative Study on the Role of DPT on the Formation of HMX in Semi-Batch and Continuous Process

Autor:	V. L. Narasimhan, S. Radhakrishnan, T. Soman, K. Sunil Kumar
Rok vydání:	2008
Předmět:	Physics and Astronomy (miscellaneous) Chemistry Scientific method Yield (chemistry) Thermodynamics
Zdroj:	Journal of Energetic Materials. 26:102-114
ISSN:	1545-8822 0737-0652
Popis:	3,7-Dinitro-1,3,5,7-tetrazabicyclo-[3,3,1]nonane (DPT) is a key intermediate in the preparation of octahydro-1,3,5,7-tetranitro 1,3,5,7-tetrazocine (HMX), one of the most powerful high-melting explosives. The present investigation focuses on DPT formation during semi-batch and continuous processes. Qualitative and quantitative picture has been brought out to realize the role of DPT in HMX formation. The study reveals that only two thirds of DPT is formed in the continuous process as compared to that of semi-batch process. The calculated final yield of HMX on reaching steady state in the continuous process is comparable to the semi-batch process. This study also illustrates the usefulness in understanding the role of DPT in the final yield of HMX.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e1a4d342f3e3bafd27458de7678b5155 https://doi.org/10.1080/07370650701801838 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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