Synthesis, characterization, and catalytic performance of Aluminum and Tin Compounds with β -diketiminato ligand
| Autor: | Yi Ding, Wenling Li, Mingdong Zhong, Xiaoli Ma, Yashuai Liu, Xin Liu, Ying Yang, Zhi Yang |
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| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Ligand Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry 0104 chemical sciences Catalysis Inorganic Chemistry Hydroboration chemistry Main group element Yield (chemistry) Materials Chemistry Proton NMR Physical and Theoretical Chemistry Tin Single crystal |
| Zdroj: | Journal of Organometallic Chemistry. 868:55-60 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2018.05.001 |
| Popis: | Two new tin (II) and tin (IV) compounds [LSnCl] (1) and [LSnCl3] (2), bearing the β-diketiminato ligand LH (L = HC(CMeNAr)2, Ar = 2,6-Et2C6H3) were synthesized by the reactions of LH with n-BuLi, then respectively with SnCl2 and SnCl4. Two new aluminum alkyl compounds, [LAlMe2] (3) and [LAlEt2] (4), were synthesized in high yield from the reactions of LH with AlMe3 and AlEt2, respectively. Compound [LAlI2] (5) was synthesized from the reaction of 3 with I2 in good yield. All these main group metal compounds bearing β-diketiminato ligand LH were fully characterized by 1H NMR and 13C NMR spectroscopy, and elemental analysis. Meanwhile, compounds 1, 2, 3, and 5 were characterized by single crystal X-ray structural analysis. Moreover, the well-defined compounds 1–4 were investigated to show good catalytic activity in hydroboration of terminal alkynes. |
| Databáze: | OpenAIRE |
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