Practical Preparation of Octa- and Tetrabromoperylene Diimides and Derivatives Thereof
| Autor: | L. Labanauskas, Augustina Jozeliūnaitė, Romualdas Striela, Edvinas Orentas |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Hydrazine chemistry.chemical_element Regioselectivity Chromophore 010402 general chemistry 01 natural sciences Sulfur Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Diimide Nucleophilic substitution Organic chemistry Hydrate Perylene |
| Zdroj: | Synthesis. 49:5176-5182 |
| ISSN: | 1437-210X 0039-7881 |
| DOI: | 10.1055/s-0036-1589088 |
| Popis: | A mild synthesis of fully brominated perylene dianhydride and diimides in one step from easily available unsubstituted precursors is presented. The partial reduction of ortho-bromo substituents with hydrazine hydrate allowed for a gram-scale synthesis of a valuable intermediate, 1,6,7,12-tetrabromoperylene diimide. Several new twisted fully core-substituted perylene diimide derivatives having sulfur, nitrogen, or oxygen substituents were synthesized using regioselective nucleophilic substitution reactions. |
| Databáze: | OpenAIRE |
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