Robust thermoplastic polyurethane elastomers prepared from recycling polycarbonate
| Autor: | Huang Yu-Hsiang, Ying-Hsiao Chen, Chi-An Dai, Li-Yun Chen, Ru-Jong Jeng, Huang Ying-Chi, Chien-Hsin Wu, Shenghong A. Dai |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Materials science Thermoplastic Polymers and Plastics Organic Chemistry 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Elastomer 01 natural sciences Isocyanate 0104 chemical sciences chemistry.chemical_compound Thermoplastic polyurethane Monomer Aminolysis chemistry Chemical engineering visual_art Materials Chemistry visual_art.visual_art_medium Polycarbonate 0210 nano-technology |
| Zdroj: | Polymer. 212:123296 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/j.polymer.2020.123296 |
| Popis: | Polymer properties along with recycling processes remain a constant challenge for post-recycled polymers. In this study, the development of recycling feasibility, monomers reactivity, and the chemical-recycled polymer properties from polycarbonate (PC) waste were demonstrated. Through selective aminolysis under mild conditions, the reduced molecular-weight products (or monomer mixtures) with newly incorporated flexible-ether linkages as building blocks were realized. By using the commodity monomers such as isocyanate reagents, monomer mixtures were readily to be re-connected into polyurethanes in one-pot process without prior purification of the recycled monomer mixtures. Due to the presence of urethane groups, the enhanced reactivity of the terminal phenolic hydroxyl groups of the monomer mixtures toward isocyanate groups would afford high molecular weights over ~80,000 g/mol for thermoplastic polyurethanes (TPUs). Moreover, by taking advantage of low melting point polyether-type polyols along with optimizing processing conditions, the TPUs exhibited a unique phase separation morphology with domain sizes ranging from ~10 nm to ~25 nm as investigated by using small angle X-ray scattering (SAXS) measurements. This work demonstrate that the PC waste was fully transformed into TPUs which exhibited improved elastomeric properties. |
| Databáze: | OpenAIRE |
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