First asymmetric total synthesis of (+)-steganacin determination of absolute stereochemistry
Autor: | Kenji Koga, Kiyoshi Tomioka, Tsuneo Ishiguro |
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Rok vydání: | 1980 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 21:2973-2976 |
ISSN: | 0040-4039 |
DOI: | 10.1016/0040-4039(80)88012-9 |
Popis: | (+)-Steganacin was synthesized in a new and highly specific asymmetric pathway based on the novel application of chiral γ-lactone as a chiral synthon. By this synthesis the absolute stereochemistry of natural (−)-steganacin could be determined in unequivocal way. |
Databáze: | OpenAIRE |
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