ChemInform Abstract: Homogeneous Catalytic Hydrosilylation of Pyridines

Autor:	Anne-Marie Lebuis, Leijun Hao, Hee-Gweon Woo, Ronghua Shu, Edmond Samuel, Ying Mu, John F. Harrod
Rok vydání:	2010
Předmět:	Hydroboration chemistry.chemical_compound Catalytic cycle Silylation Chemistry Hydrosilylation Hydride Pyridine Regioselectivity General Medicine Medicinal chemistry Catalysis
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
Popis:	The color change from yellow to violet allows the formation of the intermediate [Cp2 Ti(SiHMePh)(pyridine)] to be monitored in the reaction of PhMeSiH2 with a pyridine in the presence of the precatalyst [Cp2 TiMe2 ] [Eq. (a)]; the hydride [Cp2 TiH] is postulated to be the key intermediate in the catalytic cycle. The regioselective hydrosilylation of pyridine and also substituted pyridines can be catalyzed by the titanocene [Cp2 TiMe2 ]. R=Me, CO2 Et.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dd76e48182996524880b363d4dcbaec5 https://doi.org/10.1002/chin.199917065 Zobrazit plný text záznamu Plný text