Reactivity of bromosilylenoid with heterocumulenes
| Autor: | Seo Hyeon Park, Jun Hyun Song, Hyeon Mo Cho, Myong Euy Lee |
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| Rok vydání: | 2015 |
| Předmět: |
Substitution reaction
Phenyl isothiocyanate Organic Chemistry Cleavage (embryo) Ring (chemistry) Biochemistry Medicinal chemistry Inorganic Chemistry Silanol chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Reactivity (chemistry) Silylenoid Physical and Theoretical Chemistry Phenyl isocyanate |
| Zdroj: | Journal of Organometallic Chemistry. :128-131 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2015.09.016 |
| Popis: | Sila-heterocycles, ditrisyldibromodisiladioxetane (trisyl = C(SiMe 3 ) 3 ) 2 and ditrisyldibromodithiadisiletane 3 , were generated at a low temperature from the reaction of trisylbromosilylenoid 1 with heterocumulenes such as phenyl isocyanate and phenyl isothiocyanate. The 29 Si-NMRs of sila-heterocycles were then investigated. The reaction of cyclic compounds 2 and 3 with MeOH gave dimethoxy(trisyl)silanol 4 and dimethoxy(trisyl)silanethiol 5 , respectively, through ring cleavage and substitution reactions. This work is the first investigation of the reactivity of silylenoid with heterocumulenes. |
| Databáze: | OpenAIRE |
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