Formation of chlorinated dibenzoselenophenes by thermal reaction of hexachlorobiphenyls with selenium
| Autor: | Max Wolfensberger, Klaus Peter Segebarth, Ivan Samuel Dolezal |
|---|---|
| Rok vydání: | 1991 |
| Předmět: |
Environmental Engineering
Chemistry Health Toxicology and Mutagenesis Low resolution Public Health Environmental and Occupational Health chemistry.chemical_element Exhaust gas General Medicine General Chemistry Chlorinated Dibenzofurans Mass spectrometry Pollution Incineration Environmental chemistry Environmental Chemistry Gas chromatography Thermal reaction Selenium |
| Zdroj: | Chemosphere. 23:569-582 |
| ISSN: | 0045-6535 |
| DOI: | 10.1016/0045-6535(91)90279-m |
| Popis: | Mono- to tetrachlorinated dibenzoselenophenes, the selenium analogs of chlorinated dibenzofurans, and in addition dibenzoselenophene, are shown to be formed by thermal reaction of hexachlorobiphenyls with selenium. The new compounds were characterized and detected by high resolution gas chromatography - low resolution mass spectrometry. Dibenzoselenophene was tentatively identified in an exhaust gas sample from a hazardous waste incinerator. To our knowledge the environmental significance and the toxicology of dibenzoselenophenes is unknown; due to the structural similarities of chlorinated dibenzofurans and dibenzoselenophenes similar properties can however be taken into consideration. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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