Experimental, theoretical investigations on second order nonlinear optical solicitations of Anilinium Hydrogen Sulfate (AHS)

Autor:	P. Vivek, Ro. Mu. Jauhar, M. Kowsalya, Ananth Steephen, M. Rekha, G. Saravana Kumar
Rok vydání:	2021
Předmět:	Materials science Band gap business.industry Atomic and Molecular Physics and Optics Crystal Nonlinear optical Nonlinear system Optics Vaporization Thermal Physical chemistry Orthorhombic crystal system Reactivity (chemistry) business
Zdroj:	Journal of Optics. 51:327-335
ISSN:	0974-6900 0972-8821
DOI:	10.1007/s12596-021-00763-2
Popis:	A novel nonlinear semiorganic optical single crystalline material, anilinium hydrogen sulfate (AHS), was blended via slow vaporization process. The AHS crystal morphology was predicted to fling light on the development rate and to reveal the prominent facets. The AHS belongs to orthorhombic crystal structure and has Pca21 non-centrosymmetric space group. The energy gap, global reactivity descriptors, linear and nonlinear optical (NLO) specifications of AHS at molecular base were calculated at B3LYP/6-31G (d,p) level. The mechanical, optical and thermal tests performed on AHS crystal showed superior properties and its suitability for NLO device applications. In addition, the studies revealed that the AHS crystal is having phase matching behavior.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dccff53061bc300cb2fe6e1a77d1b749 https://doi.org/10.1007/s12596-021-00763-2 Zobrazit plný text záznamu Full text from SpringerLink