INTERMEDIATES IN THE PHOTOCHEMICAL REACTIONS OF CAMPHORQUINONE WITH ALIPHATIC ALDEHYDES

Autor:	Kazuhiro Maruyama, Tomoji Takahashi
Rok vydání:	1974
Předmět:	chemistry.chemical_classification Chemistry CIDNP Radical Ionic bonding General Chemistry Hydrogen atom abstraction Photochemistry Aldehyde
Zdroj:	Chemistry Letters. 3:467-470
ISSN:	1348-0715 0366-7022
Popis:	The dynamic aspects of photochemical reactions of camphorquinone with aliphatic aldehydes were investigated by means of CIDNP. Besides that the two types of stable products (1)–(3) could be produced through ionic rearrangement of unstable intermediates (6), (7) arose from radical pair (5), the reverse hydrogen atom abstraction reaction was found to occur between the two radicals resulted from the reaction of photo-excited camphorquinone and aldehyde.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dbe9c460c8a1e37b56be02c1999b5dc3 https://doi.org/10.1246/cl.1974.467 Zobrazit plný text záznamu