INTERMEDIATES IN THE PHOTOCHEMICAL REACTIONS OF CAMPHORQUINONE WITH ALIPHATIC ALDEHYDES

Autor: Kazuhiro Maruyama, Tomoji Takahashi
Rok vydání: 1974
Předmět:
Zdroj: Chemistry Letters. 3:467-470
ISSN: 1348-0715
0366-7022
Popis: The dynamic aspects of photochemical reactions of camphorquinone with aliphatic aldehydes were investigated by means of CIDNP. Besides that the two types of stable products (1)–(3) could be produced through ionic rearrangement of unstable intermediates (6), (7) arose from radical pair (5), the reverse hydrogen atom abstraction reaction was found to occur between the two radicals resulted from the reaction of photo-excited camphorquinone and aldehyde.
Databáze: OpenAIRE