Ethyl-β-chlorovinyl ether
Autor: | D. A. van Dorp, O. Stephenson, J. F. Arens |
---|---|
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Recueil des Travaux Chimiques des Pays-Bas. 70:289-296 |
ISSN: | 0165-0513 |
DOI: | 10.1002/recl.19510700403 |
Popis: | The preparation of ethyl-β-chlorovinyl ether from the readily available dichloroacetal is reported. Careful fractionation of the product yields the pure cis- and trans-isomers of which only the cis-isomer gives a high yield (76%) of ethoxy-acetylene on heating with potassium hydroxide. The corresponding ethyl-β-bromovinyl ether has likewise been separated into cis- and trans-isomers. |
Databáze: | OpenAIRE |
Externí odkaz: |