A critical point related to phase transitions in electrostricted H2O close to an electrode

Autor:	I. Danielewicz-Ferchmin, A. R. Ferchmin
Rok vydání:	2004
Předmět:	Phase transition Dipole Condensed matter physics Chemistry Critical point (thermodynamics) Quantum critical point Temperature jump General Physics and Astronomy Thermodynamics Physical and Theoretical Chemistry Critical exponent Local field Heat capacity
Zdroj:	Chemical Physics Letters. 398:186-189
ISSN:	0009-2614
Popis:	It is found that phase transitions should occur between two phases of H2O with different degrees of orientational order of dipoles in a very high local field E ∼ 109 V m−1 at temperatures in the range 273–303 K. Critical point of H2O at T c E = 308 ± 5 K is predicted. The analysis is based on a rigorous equation of state. The discontinuity ΔCP of the heat capacity at the transition is calculated. A consistency of the present results with a laser temperature jump experiment at a Hg/aqueous electrolyte interface is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d8744917dd4fad354254fd71b604040e https://doi.org/10.1016/j.cplett.2004.09.051 Zobrazit plný text záznamu Full Text from ScienceDirect