Strain Effects on the Crystal Growth and Superconducting Properties of Epitaxial Niobium Ultrathin Films

Autor: K. C. Wong, C. E. Reece, W. M. Roach, A. D. Batchelor, Douglas Beringer, J. R. Skuza, Cesar Clavero, Rosa A. Lukaszew
Rok vydání: 2012
Předmět:
Zdroj: Crystal Growth & Design. 12:2588-2593
ISSN: 1528-7505
1528-7483
Popis: Superconducting ultrathin films grown epitaxially onto crystalline substrates exhibit strained epitaxial growth due to lattice mismatch, which can have a significant effect on their superconducting properties. We present a complete correlation of the surface morphology, crystal growth, strain, microstructure, and superconducting properties in single-crystal Nb(110) thin films sputter deposited on a-plane sapphire substrates. Notably, we observe that the lattice mismatch between Nb and sapphire induces the formation of a hexagonal surface structure during the first three atomic layers. This is followed by a strained bcc Nb(110) phase whose in-plane lattice parameter progressively relaxes to bulk value. Similar lattice relaxation was also observed in the direction perpendicular to the interface using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Significant perpendicular strain in films up to 30 nm thick was found to ultimately affect the superconducting properties of the Nb thin films...
Databáze: OpenAIRE