Multistep Organocatalysis for the Asymmetric Synthesis of Multisubstituted Aldehydes from Allylic Alcohols

Autor:	Hyun-Ji Oh, Hye-Young Jang, Xuan-Huong Ho
Rok vydání:	2012
Předmět:	Reaction conditions Allylic rearrangement Chemistry organic chemicals Organic Chemistry Enantioselective synthesis food and beverages chemistry.chemical_element Copper Catalysis Organocatalysis Michael reaction Organic chemistry Physical and Theoretical Chemistry Stoichiometry
Zdroj:	European Journal of Organic Chemistry. 2012:5655-5659
ISSN:	1434-193X
DOI:	10.1002/ejoc.201200863
Popis:	The combination of a copper complex and a chiral amine organocatalyst induces the formation of multifunctionalized aldehydes from aromatic and aliphatic allylic alcohols. Reactions occur with excellent levels of enantioselectivity, under environmentally benign conditions, and without involving stoichiometric amounts of chemical oxidants for the oxidation of the allylic alcohols or rigorous reaction conditions for transition-metal catalysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d733dce2bd3d40f52dd35ced3f74221b https://doi.org/10.1002/ejoc.201200863 Zobrazit plný text záznamu Plný text ve formátu PDF