The Carboxylation Reaction using Nickel Catalysts. V. The Catalytic Reaction of Propene with Nickel Carbonyl and Nickel Carbonyl-Triphenylphosphine

Autor:	Yasumasa Sakakibara, Kentaro Takagi, Sango Kunichika, Tadashi Okamoto
Rok vydání:	1971
Předmět:	Reaction mechanism Nickel Carbonyl Inorganic chemistry chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis Isobutyric acid Reaction rate chemistry.chemical_compound Nickel chemistry Carboxylation Triphenylphosphine
Zdroj:	Bulletin of the Chemical Society of Japan. 44:3405-3409
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.44.3405
Popis:	The carboxylation reaction of propene catalyzed by nickel carbonyl was studied undeer various conditions. Iso- and n-butyric acids were obtained in good yields under mild conditions in the presence of a large amount of an organic acid. The catalytic carboxylation area was examined in detail. The carboxylation reaction proceeded smoothly in tetrahydrofuran, acetic acid, and dioxane. The proportion of isobutyric acid was largest in acetic acid (72.5–77.5%). Triphenylphosphine (TPP) had a great effect on the reaction rate, the catalytic reaction area, and the product distribution. On the reaction mechanism, an active species (HNi(CO)(TPP)X) was taken to account for the experimental results.
Databáze:	OpenAIRE
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