Temperature-responsive hydrogels from cellulose

Autor:	Nobuo Donkai, Hiroshi Nishimura, Takeaki Miyamoto
Rok vydání:	1997
Předmět:	Cloud point Aqueous solution Polymers and Plastics Organic Chemistry Chemical modification Condensed Matter Physics chemistry.chemical_compound chemistry Ionic strength Cellulosic ethanol Methyl cellulose Self-healing hydrogels Polymer chemistry Materials Chemistry Cellulose
Zdroj:	Macromolecular Symposia. 120:303-313
ISSN:	1022-1360
DOI:	10.1002/masy.19971200130
Popis:	The aim of this work is to prepare the temperature-responsive cellulosic hydrogels undergoing a large volume change in an aqueous solution on heating or cooling. To this end, we prepared O-methyl cellulose (MC) and O-(2-hydroxy-3-butoxypropyl) cellulose (HBPC) which precipitate out of solution on heating without forming gel. MC and HBPC derivatives prepared by homogeneous reactions were proved to be promising raw materials for the cellulosic hydrogels mentioned above The results on the phase separation of the derivatives were discussed in terms of the distribution of substituents along the cellulose chain and in the anhydroglucose units
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d6e5bfd987502c9d47fa83ade02b2a0a https://doi.org/10.1002/masy.19971200130 Zobrazit plný text záznamu Plný text