Experimental and theoretical study of the pyrolysis of trichlorosilane

Autor:	E. A. Chernyshev, T. L. Krasnova, E. A. Abronin, A. P. Sergeev, A. B. Petrunin, E. S. Abramova
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Chemistry Trichlorosilane Radical Inorganic chemistry Organic chemistry General Chemistry Mass spectrometry Pyrolysis
Zdroj:	Russian Chemical Bulletin. 46:1582-1585
ISSN:	1573-9171 1066-5285
Popis:	Pyrolysis of trichlorosilane (TCS) and copyrolysis of TCS with 1,3-butadiene were studied. The enthalpies and activation energies for the reactions of the products of TCS pyrolysis were found by quantum-chemical calculations. A direct study of the pyrolysis of TCS by mass spectrometry was carried out. Based on the thermochemical parameters found by quantum-chemical calculations and on the results of GLC and mass spectrometry concerning the composition of the pyrolysis products, it was concluded that the pyrolysis of TCS follows a scheme that includes formation of radicals and silylenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d5a32117ea0888e4ae1d8ec12586c8e1 https://doi.org/10.1007/bf02502944 Zobrazit plný text záznamu Full text from SpringerLink