| Popis: |
We investigate the role of the addition of an organic solvent to an ionic liquid electrolyte for the performance of lithium–sulphur (Li–S) batteries. We find that with a mixed electrolyte, formed by adding 10 wt% 1,3-dioxolane (DIOX) to an ionic liquid, the capacity of a Li–S cell is more than doubled, the rate capability and the cycling performance considerably improved, compared to a cell utilizing a neat ionic liquid electrolyte. The improved performance can be correlated with an enhanced ion transport, evidenced by an increased ionic conductivity and higher limiting current density, directly related to a decrease in viscosity and glass transition temperature of the mixed electrolytes. We show that this in turn is linked to a change in the local environment of the Li-ions where the organic solvent is incorporated in the coordination shell. In addition we show that the mixed electrolytes have a considerably higher thermal stability, in particular a dramatically increased flash point, and improved low temperature properties with respect to a conventional organic solvent based electrolyte currently used for Li–S batteries. |
