Oxidation periodique de derive´s du saccharose

Autor:	Julio Mentech, Agne`s Badel, Ge´rard Descotes
Rok vydání:	1990
Předmět:	Sucrose Organic Chemistry Disaccharide Ketose Periodic acid Periodate General Medicine Nuclear magnetic resonance spectroscopy Cleavage (embryo) Biochemistry Medicinal chemistry Analytical Chemistry chemistry.chemical_compound chemistry Organic chemistry Selectivity
Zdroj:	Carbohydrate Research. 205:323-331
ISSN:	0008-6215
DOI:	10.1016/0008-6215(90)80150-2
Popis:	The periodate oxidation of some derivatives of sucrose at primary positions is generally selective for the D-glucopyranoside group. A cleavage at C-2-C3 or C-3-C-4 positions was observed for the 6,1',6'-tri-O-trityl and 6,1',6'-tri-O-(tert-butyldemethylsilyl) derivatives, respectively. The periodate oxidation was more complete for all other derivatives with a cleavage at C-2-C-3 and C-3-C-4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d3c7b6607417b4d1facd4af8f5cad99d https://doi.org/10.1016/0008-6215(90)80150-2 Zobrazit plný text záznamu