Unified representation of MQMAS and STMAS NMR of half-integer quadrupolar nuclei

Autor:	Frank Engelke, Francis Taulelle, Clarisse Huguenard, Jean-Paul Amoureux
Rok vydání:	2002
Předmět:	Renormalization NMR spectra database Magic angle Nuclear magnetic resonance Solid-state nuclear magnetic resonance Chemistry Quantum mechanics Isotropy General Physics and Astronomy Half-integer Physical and Theoretical Chemistry Anisotropy Spectral line
Zdroj:	Chemical Physics Letters. 356:497-504
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(02)00398-6
Popis:	High resolution solid state NMR has been achieved for nuclei that exhibit quadrupolar interaction to the second order by MQMAS and more recently by STMAS. Both methods extend to several variants, 3QMAS, 5QMAS, … for MQMAS as well as ST 1 MAS, ST 2 MAS,… for STMAS. These experiments contain the same information content i.e. anisotropic second-order powder pattern and isotropic terms. A unified representation allows us to display the 2D spectra independently of the method used. Direct comparison of any such spectra is therefore straightforward and does not need any further renormalization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d359a380d3bf6c327cb33911eee852e0 https://doi.org/10.1016/s0009-2614(02)00398-6 Zobrazit plný text záznamu Full Text from ScienceDirect