Intramolecular nucleophilic attack at silicon in o-silylbenzyl alcohols. Generation of allyl and benzyl anion equivalents

Autor:	Anne M. Hudrlik, Paul F. Hudrlik, Yassin A. Jeilani
Rok vydání:	2011
Předmět:	Silicon Silylation Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Ion Benzaldehyde chemistry.chemical_compound chemistry Nucleophile Intramolecular force Drug Discovery Electrophile Benzophenone Organic chemistry
Zdroj:	Tetrahedron. 67:10089-10096
ISSN:	0040-4020
DOI:	10.1016/j.tet.2011.09.127
Popis:	Substituted silyl ethers of o-bromobenzyl alcohols and the derived o-silylbenzyl alcohols were used to transfer allyl and benzyl groups from silicon to the electrophiles benzaldehyde and benzophenone in excellent yields. γ-Oxidosilane intermediates (and possibly hypercoordinated silicon intermediates) are postulated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d1e4463470e3002f4def449096730c5d https://doi.org/10.1016/j.tet.2011.09.127 Zobrazit plný text záznamu Full Text from ScienceDirect