Reaction modes of oxidative dimerization of epoxycyclohexenols

Autor:	Hiroyuki Osada, Mitsuru Shoji, Yusuke Kodera, Satoshi Kishida, Isamu Shiina, Hideaki Kakeya, Yujiro Hayashi
Rok vydání:	2003
Předmět:	chemistry.chemical_compound Chemistry Hydrogen bond Stereochemistry Organic Chemistry Drug Discovery health occupations Epoxide macromolecular substances Oxidative phosphorylation environment and public health Biochemistry Diels–Alder reaction
Zdroj:	Tetrahedron Letters. 44:7205-7207
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(03)01781-7
Popis:	Of the 16 possible modes of the oxidation-6π-electrocylization-Diels–Alder reaction cascade for an epoxyquinone, and eight for a 2-alkenyl-3-hydroxymethyl-2-cyclohexen-1-one, only the endo - anti (epoxide) -anti (Me)-hetero and endo - anti (Me)-hetero are respectively observed, while both the endo - anti (epoxide) -anti (Me)-hetero and exo - anti (epoxide) -anti (Me)-homo reaction modes occur with epoxy-4-hydroxycyclohexenones owing to a hydrogen-bonding interaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d0a50be4b750a63b43aab6f152ce0950 https://doi.org/10.1016/s0040-4039(03)01781-7 Zobrazit plný text záznamu Full Text from ScienceDirect