Deep Eutectic Solvents As Tuning Media Dissolving Cu+ Used in Facilitated Transport Supported Liquid Membrane for Ethylene/Ethane Separation
| Autor: | Rong Deng, Wenjun Tao, Yongli Sun, Huawei Yang, Haozhen Dou, Hanrong Bi, Bin Jiang, Baoyu Wang |
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| Rok vydání: | 2017 |
| Předmět: |
Facilitated diffusion
General Chemical Engineering Inorganic chemistry Energy Engineering and Power Technology 02 engineering and technology Permeation 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chloride 0104 chemical sciences chemistry.chemical_compound Fuel Technology Membrane chemistry medicine Absorption (chemistry) 0210 nano-technology Dissolution Choline chloride medicine.drug Eutectic system |
| Zdroj: | Energy & Fuels. 31:11146-11155 |
| ISSN: | 1520-5029 0887-0624 |
| DOI: | 10.1021/acs.energyfuels.7b01305 |
| Popis: | In the petrochemical industry, it is critical to separate the light olefins/paraffins mixtures via an efficient and economic method. In this work, a series of deep eutectic solvents (DESs) (choline chloride (ChCl)-glycerol (G), ChCl-ethylene glycol (EG), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl])-G, and [Bmim][Cl]-EG) dissolving CuCl were used as novel membrane liquids to fabricate supported liquid membranes (SLMs) for the C2H4/C2H6 mixture separation. Interactions based on a hydrogen bond network in different DESs were characterized by time-of-flight mass spectroscopy (TOF-MS), nuclear magnetic resonance (1H NMR), and Fourier transform infrared (FT-IR) spectroscopy. Moreover, by absorption experiments, the Cu+ activity was quantitatively described based on a first-order equilibrium model. The effects of DESs species, CuCl concentration, transmembrane pressure, temperature, and time on separation performances were investigated by C2H4/C2H6 mixture permeation experiments. CuCl/ChCl-EG-based SLMs pos... |
| Databáze: | OpenAIRE |
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