Reaction of ?,?,?-trihydroperfluoroalkyl esters of phosphorous acid with polyfluorocarbonyl compounds

Autor: O. V. Verenikin, K. I. Pasevina, A. I. Rapkin, A. V. Fokin, Yu. N. Studnev, A. F. Kolomiets
Rok vydání: 1981
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:1344-1347
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf01418013
Popis: 1. The α,α,ω-trihydroperfluoroalkyl esters of phosphorous acid react with polyfluorocarbonyl compounds the same as unfluorinated phosphites, but exhibit a lower reactivity. 2. The reaction of tris (1,1,3-trihydroperfluoropropyl) phosphite with the hydrates of hexafluoroacetone and trifluoroacetaldehyde respectively givesα-monohydroperfluoroisopropyl bis (1,1,3-trihydroperfluoropropyl) phosphate and 2,2,2-trifluoroethyl bis (1,1,3-trihydroperfluoropropyl) phosphate.
Databáze: OpenAIRE