Reaction of ?,?,?-trihydroperfluoroalkyl esters of phosphorous acid with polyfluorocarbonyl compounds
Autor: | O. V. Verenikin, K. I. Pasevina, A. I. Rapkin, A. V. Fokin, Yu. N. Studnev, A. F. Kolomiets |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:1344-1347 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf01418013 |
Popis: | 1. The α,α,ω-trihydroperfluoroalkyl esters of phosphorous acid react with polyfluorocarbonyl compounds the same as unfluorinated phosphites, but exhibit a lower reactivity. 2. The reaction of tris (1,1,3-trihydroperfluoropropyl) phosphite with the hydrates of hexafluoroacetone and trifluoroacetaldehyde respectively givesα-monohydroperfluoroisopropyl bis (1,1,3-trihydroperfluoropropyl) phosphate and 2,2,2-trifluoroethyl bis (1,1,3-trihydroperfluoropropyl) phosphate. |
Databáze: | OpenAIRE |
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