Partition of the Li,Cs‖F,Cl,Br quaternary mutual system into simplexes and investigation of the LiF-CsF-CsCl-CsBr tetrahedron

Autor: I. K. Garkushin, M. V. Chugunova, E. M. Dvoryanova
Rok vydání: 2011
Předmět:
Zdroj: Russian Journal of Inorganic Chemistry. 56:1988-1996
ISSN: 1531-8613
0036-0236
DOI: 10.1134/s0036023611120321
Popis: A quaternary mutual system of fluorides, chlorides, and bromides of lithium and cesium was partitioned into simplexes by a geometric method and by a graph method. Phase transformations and chemical reactions in the bordering ternary mutual systems were described. A conversion line was experimentally studied, and information on crystallizing phases within the composition prism of the Li,Cs‖F,Cl,Br system was obtained and confirmed by X-ray powder diffraction data. The characteristics of the minimum in the LiF-CsF-CsCl-CsBr tetrahedron were determined.
Databáze: OpenAIRE