Energy gap law for electron transfer rates in polymer glasses

Autor:	A.V. Barzykin, M. Tachiya
Rok vydání:	2005
Předmět:	Electron transfer rate chemistry.chemical_classification Electron transfer Reaction rate constant chemistry Condensed matter physics Computational chemistry Band gap General Physics and Astronomy Polymer Physical and Theoretical Chemistry Saturation (magnetic) Fast mode
Zdroj:	Chemical Physics. 319:222-225
ISSN:	0301-0104
DOI:	10.1016/j.chemphys.2005.03.036
Popis:	Energy gap dependence of the electron transfer rate in a system with two distinct classical relaxation modes is discussed. It is shown that when the relaxation slows down, only the fast mode determines the width of the gap-law curve while the position of the maximum is related to the full reorganization energy and does not change. Frozen relaxation leads to saturation of the rate constant with respect to an increase in the electronic coupling.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ceb1c0b144a33180b86f34dbaaaf43ba https://doi.org/10.1016/j.chemphys.2005.03.036 Zobrazit plný text záznamu Full Text from ScienceDirect