Hydrogen bonding and proton transfer in the complexes between pyridinium cations and amines in acetone solution

Autor:	Zenon Pawlak, Maria Tusk, Stefan Kuna
Rok vydání:	1982
Předmět:	chemistry.chemical_classification Base (chemistry) Chemistry Hydrogen bond Inorganic chemistry General Chemistry Glass electrode law.invention chemistry.chemical_compound law Stability constants of complexes Acetone Anhydrous Amine gas treating Pyridinium
Zdroj:	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 78:2685
ISSN:	0300-9599
Popis:	The formation constants of the complexes formed between the pyridinium cation and nineteen amines have been determined in anhydrous acetone. An electrochemical cell used a glass electrode as pH sensor. A correlation exists between the base strength of an amine B and its tendency to form heteroconjugated complexes. The relationships between the overall equilibria constants, K0, proton transfer constants, KPT, and formation constants, K(PyHB+), and ΔpKa in acetone are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ce5d4977b1812bdfaedc6ea90ed69762 https://doi.org/10.1039/f19827802685 Zobrazit plný text záznamu