Substitution of Acyl for Acetyl with N-Acylbenzotriazoles Catalyzed by Samarium Triiodide

Autor:	Xiaofei Jia, Xiaoxia Wang, Xuefei Zou, Guanqun Xie
Rok vydání:	2007
Předmět:	Substitution reaction Samarium chemistry.chemical_compound chemistry Acetylacetone Substitution (logic) chemistry.chemical_element General Medicine Triiodide Medicinal chemistry Catalysis Open air
Zdroj:	ChemInform. 38
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200744022
Popis:	Catalyzed by samarium triiodide (SmI3), substitution of acyl with N‐acylbenzotriazoles for acetyl in acetoacetic esters and acetylacetone proceeds smoothly under neutral conditions in open air, affording the corresponding β‐keto esters and β‐diketones in good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cdd5df0f6eb81f72f83a839369f19ae1 https://doi.org/10.1002/chin.200744022 Zobrazit plný text záznamu Plný text