Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties

Autor:	Vasili Miluykov, Yulia Krupskaya, Vladislav Kataev, Oleg G. Sinyashin, Rüdiger Klingeler, Ilya Bezkishko, Evamarie Hey-Hawkins, Dmitry B. Krivolapov, Anupama Parameswaran, Olga N. Kataeva, Bernd Büchner
Rok vydání:	2010
Předmět:	Electron density Magnetic moment Magnetism Chemistry Organic Chemistry Inorganic chemistry chemistry.chemical_element Manganese Magnetic exchange Inorganic Chemistry Crystallography Intramolecular force Redistribution (chemistry) Physical and Theoretical Chemistry
Zdroj:	Organometallics. 29:1339-1342
ISSN:	1520-6041 0276-7333
Popis:	The reaction of Mn(CO)5Br with 1-trimethyltin-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-diene leads to formation of binuclear manganese(I) complexes with bridging 1,2-diphosphacyclopentadienyl ligands exhibiting magnetic properties apparently similar to Mn(II) compounds due to intramolecular redistribution of the electron density. Variation of peripheral ligands of binuclear complexes provides control over the magnitude of the magnetic moment, the contribution of the orbital magnetism, and the strength of the magnetic exchange.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd374b25775fe4a4d8dee5b6a3e5442b https://doi.org/10.1021/om900764q Zobrazit plný text záznamu