Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

Autor: N. V. Murav´yov, S. V. Nikitin, Alla N. Pivkina, G. V. Pokhvisneva, G. A. Smirnov, Pavel V. Dorovatovskii, T. S. Kon´kova, Yu. V. Nelubina, O. A. Luk´yanov, N. I. Shlykova, T. V. Ternikova
Rok vydání: 2017
Předmět:
Zdroj: Russian Chemical Bulletin. 66:1066-1073
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-017-1855-z
Popis: The key steps of the synthesis of two high energy compounds, namely, 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane, were optimized. Their enthalpy of formation, density, impact and friction sensitivity, and thermal stability were experimentally determined.
Databáze: OpenAIRE