| Autor: |
Konrad T. Wu, Chanaka Mendis, Ahmed Abrahim, Robert Oldmixon |
| Rok vydání: |
1993 |
| Předmět: |
|
| Zdroj: |
Chemical Physics Letters. 210:118-122 |
| ISSN: |
0009-2614 |
| DOI: |
10.1016/0009-2614(93)89110-4 |
| Popis: |
The line shapes of the Balmer lines ( n = 3, 4) produced from the reaction between methylene chloride and metastable helium atom He (2 3 S) in a high vacuum chamber were analyzed, and the nascent translational energies were estimated from the Doppler broadening profiles. The fractions of available energy partitioned into translational energy can be explained by a simple impulsive model incorporating vibrational excitation due to geometry change during transition from the parent to product fragments. The precursor state was assigned to a Rydberg component converging to the upper state of CH 2 Cl + 2 . Subsequent predissociation of the Rydberg state leads to the production of H*. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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