Selective Glycosylation with the Amino SugarD-Forosamine for the Synthesis of Spinosyns and Its Analogues

Autor:	Simon Biller, Lutz F. Tietze, Mohammad M. Baag, Simone Dietz, Judith Hierold, Nina Schützenmeister, Timo Scheffer
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Glycosylation Amino sugar 010405 organic chemistry Stereochemistry Organic Chemistry chemistry.chemical_element Glycoside Forosamine Alcohol 010402 general chemistry Iodine 01 natural sciences 3. Good health 0104 chemical sciences chemistry.chemical_compound chemistry Organic chemistry Physical and Theoretical Chemistry Selectivity Sugar
Zdroj:	European Journal of Organic Chemistry. 2013:7305-7312
ISSN:	1434-193X
DOI:	10.1002/ejoc.201300983
Popis:	For the synthesis of novel spinosyn analogues, the selective introduction of the 2-deoxyamino sugar, D-forosamine, necessary for their bioactivity, is described. The reactions of different alcohol acceptors with the D-forosamine donor in the presence of iodine and Et3SiH gave the corresponding glycosides in yields of up to 96 % and with an α/β selectivity of 2:3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c9c09e9e19efd1499c60e835e5957565 https://doi.org/10.1002/ejoc.201300983 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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