Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles

Autor:	V. M. Mokhov, Yu. V. Popov, K. V. Shcherbakova
Rok vydání:	2016
Předmět:	Formamide Primary (chemistry) 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Reductive amination 0104 chemical sciences Catalysis chemistry.chemical_compound Colloid Nickel chemistry Organic chemistry Organic synthesis Acetamide
Zdroj:	Russian Journal of General Chemistry. 86:798-805
ISSN:	1608-3350 1070-3632
Popis:	Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in the presence of primary amines led to the predominant formation of unsymmetrical secondary amines. In the presence of secondary amines hydrogenation of nitrites provided enamines as main products. Hydrogenation of nitriles in the presence of formamide or acetamide afforded formyl or acetyl derivatives of primary amines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c98d4b7b84253ef1c8a6690f203c695e https://doi.org/10.1134/s107036321604006x Zobrazit plný text záznamu Plný text ve formátu PDF