Boron atom reactions with the halomethanes

Autor:	P. Davidovits, D. J. Sardella, M. B. Tabacco, C. T. Stanton
Rok vydání:	1985
Předmět:	Chemistry Inorganic chemistry General Physics and Astronomy MNDO chemistry.chemical_element Boron atom chemistry.chemical_compound Reaction rate constant Fluorine Chlorine Carbon tetrachloride Reactivity (chemistry) Physical and Theoretical Chemistry Boron
Zdroj:	The Journal of Chemical Physics. 83:5595-5601
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.449683
Popis:	Rate constants have been measured for the reactions of boron atoms with a series of halomethanes. The experiments were performed in a linear flow tube apparatus at 300 K. The measured rate constants in units of cm3 molecule−1 s−1 are CCl4:9.5×10−11; CCl3H:4.8×10−11; CCl2H2:6.2×10−11; CClH3:1.4×10−11; CCl3F:3.1×10−11; CCl2F2:5.5×10−12; CClF3:1.7×10−13; CF4
Databáze:	OpenAIRE
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