X-ray spectral study of the nature of electronic interactions in transition metal dithiocarbamates
| Autor: | G. K. Parygina, S. B. Érenburg, S. M. Zemskova, N. V. Bausk, É. S. Fomin, L. N. Mazalov, S. V. Larionov |
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| Rok vydání: | 1998 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Ligand chemistry.chemical_element Electronic structure Zinc Photochemistry Spectral line Inorganic Chemistry Metal Nickel Crystallography chemistry Transition metal visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Dithiocarbamate |
| Zdroj: | Journal of Structural Chemistry. 39:923-927 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1007/bf02903606 |
| Popis: | SKβ spectra are studied for a series of nickel(II), zinc(II), and cadmium(II) dithiocarbamate complexes. Model quantum chemical calculations of the electronic structure of planar chelate rings are reported. It is shown that the metal-ligand interaction forming a coordination bond between the dithiocarbamate ligand and the metal mainly involves the nonbonding n-electrons and the weakly bonding π-electrons localized on the sulfur atoms. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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