ChemInform Abstract: Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes

Autor:	William E. Brenzovich, F. Dean Toste, Jean-François Brazeau
Rok vydání:	2011
Předmět:	Hydroxylation chemistry.chemical_compound Chemistry Intramolecular force Oxidative coupling of methane General Medicine Electrophilic aromatic substitution Combinatorial chemistry Coupling reaction Boronic acid Catalysis
Zdroj:	ChemInform. 42
ISSN:	0931-7597
DOI:	10.1002/chin.201108040
Popis:	During continuing studies with a novel oxidative gold oxyarylation reaction, arylsilanes were found to be competent coupling partners, providing further evidence for an intramolecular electrophilic aromatic substitution mechanism. While providing yields complementary to those of the previously described boronic acid methods, the use of trimethylsilanes reduces the observation of homocoupling byproducts and allows for facile intramolecular coupling reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c71c8562411c688ec0ee9760ed0e7cbf https://doi.org/10.1002/chin.201108040 Zobrazit plný text záznamu Plný text