Study of reaction of curium oxy-compound formation in molten chlorides

Autor:	A. G. Osipenko, A. V. Bychkov, A. A. Mayorshin
Rok vydání:	2009
Předmět:	Curium chemistry Inorganic chemistry Potentiometric titration chemistry.chemical_element Electrolyte Physical and Theoretical Chemistry Atmospheric temperature range Alkali metal Chemical reaction Oxygen sensor Oxygen
Zdroj:	Radiochimica Acta. 97:227-230
ISSN:	2193-3405 0033-8230
Popis:	The method of potentiometric titration using oxygen sensors with solid electrolyte membrane was applied to study the interaction of curium cations with oxygen anions in the molten alkali metal chlorides in the temperature range of 450–850 °C depending on oxy-acidity of melt. Assumptions were made concerning the ion and phase composition of the obtained compounds and the chemical reactions that take place in the melts at high temperature. Basic thermodynamic values were calculated for the resultant curium oxy-compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c633f82e6dcc826d340ebec73fba702f https://doi.org/10.1524/ract.2009.1600 Zobrazit plný text záznamu