Structures of Dinuclear Copper(II) Complexes Bridged by One Oximato, One Methoxo and One Perchlorato Ligand, and One Oximato and Two Acetato Ligands

Autor:	Setsuo Kashino, Akihiko Yatani, Wasuke Mori, Katsushi Kimura, Masashi Kinoshita, Mie Fujii, Sachiyo Sakamoto, Yasuo Nakao
Rok vydání:	2001
Předmět:	Crystallography chemistry.chemical_compound Trigonal bipyramidal molecular geometry Denticity Stereochemistry Chemistry Square pyramid Ligand chemistry.chemical_element General Chemistry Oxime Copper
Zdroj:	Bulletin of the Chemical Society of Japan. 74:2375-2376
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.74.2375
Popis:	The cation of [Cu(L1)(OMe)(ClO4)Cu(bpy)] ClO4 (1) consists of two coppers triply bridged by an oximato, a methoxo, and a perchlorato ligand, where L1 is 3-[2-(2-pyridyl)ethyl]amino-2-butanone oxime. The geometry around each copper is distorted square-pyramidal. The cation of [Cu(L1)(OAc)2Cu(bpy)]ClO4 (2), consists of two coppers triply bridged by an oximato, an unidentate and a bidentate acetato ligand. The geometry around the coppers is intermediate between a square pyramid and a trigonal bipyramid.
Databáze:	OpenAIRE
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