N-Heterocyclic carbene adducts to [Cp′FeI]2: synthesis and molecular and electronic structure
| Autor: | Constantin G. Daniliuc, Dirk Baabe, Peter G. Jones, Matthias Freytag, Marc D. Walter, Kristoffer Harms, Matthias Reiners, Miyuki Maekawa |
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| Rok vydání: | 2016 |
| Předmět: |
Spin states
010405 organic chemistry Ligand Relaxation (NMR) 010402 general chemistry 01 natural sciences Magnetic susceptibility 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Paramagnetism Crystallography chemistry Computational chemistry Density functional theory Ground state Carbene |
| Zdroj: | Inorganic Chemistry Frontiers. 3:250-262 |
| ISSN: | 2052-1553 |
| Popis: | Addition of N-heterocyclic carbenes (L = 1,3-di-tert-butylimidazol-2-ylidene (ItBu), 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene (IiPr2Me2), 1,3-mesitylimidazol-2-yildene (IMes) and 1,3-di-(2,6-di-isopropylphenyl)imidazol-2-yildene (IPr)) to the iron half-sandwich complex [Cp′FeI]2 (Cp′ = η5-1,2,4-(Me3C)3C5H2, 1) forms the neutral, 16VE adducts [Cp′FeI(L)] (2–5) in moderate to excellent yields. These complexes were structurally characterised. The NHC ligand binds strongly to the Fe(II) atom, so that no exchange is observed on the NMR and chemical time scale. Fe(II) atoms in the starting material 1 adopt a high-spin configuration (S = 2) and are weakly antiferromagnetically coupled at low temperatures. Furthermore, in contrast to previous reports on related [(η5-C5Me5)FeCl(NHC)] systems, in which the Fe(II) atoms assume an intermediate spin (S = 1), no spin state change occurs upon coordination of the NHC ligand; the Fe(II) atoms in complexes 2–5 retain their high-spin state (S = 2) as shown by solid state magnetic susceptibility and zero-field 57Fe Mossbauer spectroscopy investigations. Density functional theory (DFT) studies at the B3LYP level of theory also agree with a well separated S = 2 ground state for compounds 2–5. Surprisingly for Fe(II) high-spin systems, compounds 1–5 exhibit slow paramagnetic relaxation in their Mossbauer spectra; this can be traced to spin–spin and spin–lattice relaxation processes with unusually large spin–lattice relaxation barriers. A structural model is proposed that associates these processes with crystal packing effects. |
| Databáze: | OpenAIRE |
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