trans-Bis(O-ethylxanthato)bis(triphenylphosphine)ruthenium(III) hexafluorophosphate monohydrate

Autor: Yuko Ohuchi, Kazuo Kashiwabara, Kyoko Noda, Hideo D. Takagi, Takayoshi Suzuki
Rok vydání: 2006
Předmět:
Zdroj: Acta Crystallographica Section E Structure Reports Online. 62:m1077-m1078
ISSN: 1600-5368
DOI: 10.1107/s1600536806013420
Popis: In the monoclinic crystal structure of the title compound, trans-[Ru(C3H5OS2)2(C18H15P)2]PF6·H2O, the structure of the RuIII complex cation is very similar to that in the orthorhombic crystal of the nonhydrated complex [Noda, Ohuchi, Hashimoto, Fujiki, Itoh, Iwatsuki, Noda, Suzuki, Kashiwabara & Takagi (2006), Inorg. Chem. 45, 1349–1355]. In the present crystal structure, the P—Ru—P bond axes of the complex cations are aligned parallel to the [101] direction.
Databáze: OpenAIRE