The mutual solubility of organic-liquid membrane and aqueous phases at different water pH for the stability of SLM using Aliquat 336 as an ionic-liquid extractant
| Autor: | Kridsada Aunnankat, Ura Pancharoen, Kreangkrai Maneeintr, Thidarat Wongsawa, Tanakon Koonsang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Aqueous solution
Chemistry Inorganic chemistry Aqueous two-phase system 02 engineering and technology Aliquat 336 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry.chemical_compound Phase (matter) Ionic liquid Materials Chemistry Non-random two-liquid model Physical and Theoretical Chemistry Solubility 0210 nano-technology Ternary operation Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 292:111363 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2019.111363 |
| Popis: | Regarding supported liquid membrane (SLM), the mutual solubility of both the organic and aqueous phases has an influence on its stability. Investigation into causes of mutual solubility is very important to prevent instability of the system. This work focuses on the influence of water pH as regards the solubility and stability of SLM. For the organic phase, ionic-liquid extractant viz. Aliquat 336, combining with various organic solvents, was used. As for the aqueous phase, acidic, neutral and basic water was prepared. The solubility of the liquid-liquid ternary systems (adjusted pH water + Aliquat 336 + organic solvents) was carried out at T = 303.2 K and atmospheric pressure. Tie-line data of the ternary systems were also determined. Good correlation of tie-line data from the NRTL model and experiments was confirmed and validated by the root-mean square deviation values which were |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect