New synthesis of [RuH(CO)(PPh3)2L2][BF4] [L2=2py, 2(4-Mepy) or bpy] and X-ray crystal structure of [RuH(CO)(PPh3)2(4-Mepy)2][BF4]

Autor:	Stephen L. Gipson, J. Matt Farmer, Jason A. Kautz, Donald F. Mullica, Yohannes F. Belay, Mark S. Windmiller
Rok vydání:	1999
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography Chemistry Pyridine Materials Chemistry X-ray Crystal structure Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 285:318-321
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(98)00355-7
Popis:	The title compounds were prepared by reaction of RuH2(CO)(PPh3)3 with [C7H7][BF4] in the presence of excess pyridine, 4-picoline or 2,2′-bipyridine. The compounds were characterized by IR, 1 H and 31 P NMR, and X-ray crystallography (for the 4-Mepy complex). The spectroscopic data as well as the results of the X-ray crystal structure show that the complexes contain trans-oriented phosphines and cis-pyridines. Details of the structural content and selected bond distances and angles are internally consistent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c34d36c21c79e833ba70915b1fce2c17 https://doi.org/10.1016/s0020-1693(98)00355-7 Zobrazit plný text záznamu Full Text from ScienceDirect