Enantioselective synthesis of new 4-substituted glutamic acid derivatives

Autor:	Valérie Rolland, Alain Fruchier, M. L. Roumestant, Jean Martinez, Johny Wehbe
Rok vydání:	2004
Předmět:	Inorganic Chemistry chemistry.chemical_compound Schiff base chemistry Stereochemistry Organic Chemistry Enantioselective synthesis Organic chemistry Physical and Theoretical Chemistry Glutamic Acid Derivatives Catalysis Conjugate
Zdroj:	Tetrahedron: Asymmetry. 15:851-858
ISSN:	0957-4166
DOI:	10.1016/j.tetasy.2004.01.006
Popis:	Several new 4-substituted glutamic acid derivatives are described: 4-phosphinomethyl glutamic acid derivatives were prepared starting from (2 S )- N -Boc- tert -butyl-4-methylene glutamate. The 4-carboxymethyl and 4-aminomethyl glutamic acid derivatives were obtained using asymmetric 1,4-addition conjugate of the enolate of Schiff base 1 to unsaturated esters.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c2ac47fe1401175eb6f952598c7e87ac https://doi.org/10.1016/j.tetasy.2004.01.006 Zobrazit plný text záznamu Full Text from ScienceDirect