'Thiol–ene' click synthesis of chiral covalent organic frameworks for gas chromatography

Autor:	Cheng Yang, Xiu-Ping Yan, Jing-Xuan Guo
Rok vydání:	2021
Předmět:	Materials science Cyclohexane Renewable Energy Sustainability and the Environment General Chemistry Combinatorial chemistry chemistry.chemical_compound chemistry Covalent bond Specific surface area Citronellal Surface modification General Materials Science Thermal stability Benzene Ene reaction
Zdroj:	Journal of Materials Chemistry A. 9:21151-21157
ISSN:	2050-7496 2050-7488
Popis:	The unique properties of covalent organic frameworks (COFs), such as a large specific surface area, good stability and easy functionalization, make them have good potential in the field of separation science. However, the synthesis of chiral COFs is challenging, so the application of COFs in chiral separation is very limited. Here, we show a simple and effective “thiol–ene” click strategy to construct chiral COFs. The chiral COF CTzDva showed high thermal stability and good porosity, prompting us to explore its application in chromatographic separation. The CTzDva-based gas capillary column showed good separation of benzene/cyclohexane, and racemates (citronellal and fenchone). This work provides a promising platform for the synthesis of chiral COFs and expands the application of COFs in the field of separation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c21980c6e684136c45ca005b3ca53508 https://doi.org/10.1039/d1ta04621g Zobrazit plný text záznamu