A new 3D supramolecular compound containing 1D chains and 1D water chains

Autor:	Jing-cai Yao, Yan-ge Li, Kai Jiang, Xue-lan Mei, Lu-Fang Ma
Rok vydání:	2009
Předmět:	Inorganic Chemistry Crystallography Octahedron Chain (algebraic topology) Zigzag Hydrogen bond Chemistry Materials Chemistry Supramolecular chemistry Molecule Crystal structure Physical and Theoretical Chemistry Ion
Zdroj:	Inorganic Chemistry Communications. 12:941-944
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2009.06.027
Popis:	The first crystal structure involving the discrete unsubstituted 1,2,4-triazolate anion is reported. In the title compound, [Na2(H2O)8]n(trz)2n [trz = 1,2,4-triazolate] (1), each sodium(I) ion is coordinated by six water molecules with a slight distorted octahedron geometry. Each Na(I) are bridged by two μ2-aqua ligands and arranged in an alternating fashion to construct a 1D zigzag {[Na2(H2O)8]2+}n chain. The 3D supermolecular framework is formed with 1D {[Na2(H2O)8]2+}n chain as the assembly units, by 1D water chain and 1,2,4-triazolate anion as the hydrogen bonding spacers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c1d871b2a017d3a6c80558886775deb4 https://doi.org/10.1016/j.inoche.2009.06.027 Zobrazit plný text záznamu Full Text from ScienceDirect