Some features of the isomerization of ?-olefins in the presence of heterogenized nickel complexes

Autor:	S. A. Chernov, L. A. Makhlis, V. É. Vasserberg, D. B. Furman, O. V. Bragin, N. V. Volchkov
Rok vydání:	1983
Předmět:	chemistry.chemical_classification Chemistry chemistry.chemical_element General Chemistry Atmospheric temperature range Photochemistry Catalysis chemistry.chemical_compound Nickel Hydrocarbon Polymer chemistry Reactivity (chemistry) Triphenylphosphine Isomerization
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:509-513
ISSN:	1573-9171 0568-5230
Popis:	1. The reactivity of hydrocarbons in the presence of dicarbonyl-bis (triphenylphosphine)nickel (0) heterogenized on Al2O3 decreases in the order: 1-hexene≈4-methyl-1-pentene > 1-heptene≫-methyl-1-pentene. 2. The Ni(CO)2 (PPh3)2/Al2O3-Et3Al2Cl3 catalytic system displays high isomerization activity in a relatively narrow temperature range.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c0703f85b1af57500b7d65f4b61673cb https://doi.org/10.1007/bf00953085 Zobrazit plný text záznamu Full text from SpringerLink