Synthesis of Cluster Alkyl and Aryl Grignard Reagents in Solution

Autor:	Sergei Nikolaev, Denis A. Potapov, Irina P. Beletskaya, V. V. Smirnov, L. A. Tjurina, Stanislav E. Esipov
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Aryl Organic Chemistry Halide Inorganic Chemistry chemistry.chemical_compound Transmetalation chemistry Reagent Polymer chemistry Cluster (physics) Organic chemistry Physical and Theoretical Chemistry Fluoride Alkyl
Zdroj:	Organometallics. 23:1349-1351
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om030633x
Popis:	Cluster alkyl Grignard reagents, alkyltetramagnesium chlorides, have been obtained by exchange reaction between phenyltetramagnesium fluoride and organic halides in excess halide solution at room temperature. Transmetalation between PhCl, PhBr, and phenyltetramagnesium fluoride with the formation of PhMg4X (X = Cl, Br) has been shown to occur.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c05b86e8be2849b8a6aded97ec7f9d2a https://doi.org/10.1021/om030633x Zobrazit plný text záznamu