Composite materials based on fullerenes C60/C70 and polypropylene prepared via in situ polymerization

Autor:	A. A. Popov, A. N. Klyamkina, V. E. Muradyan, S. V. Polschikov, V. G. Krasheninnikov, A. L. Margolin, Alexander N. Shchegolikhin, P. M. Nedorezova, T. V. Monakhova
Rok vydání:	2013
Předmět:	Polypropylene Thermal oxidation Fullerene Materials science Polymers and Plastics law.invention Catalysis chemistry.chemical_compound chemistry law Tacticity Materials Chemistry Ceramics and Composites Composite material In situ polymerization Crystallization Metallocene
Zdroj:	Polymer Science Series B. 55:286-293
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090413050059
Popis:	New composite materials based on isotactic PP and fullerene were prepared via in situ polymerization with the use of an isospecific metallocene catalytic system. The stress-strain properties, thermophysical characteristics, and reactivities of composites in reactions of high-temperature decomposition, oxidation, and chemiluminescence were studied. The appreciable effect of fullerene on the thermal oxidation and crystallization behavior of composites (an increase in the crystallization temperature by 10 K) was found. It was shown that the protective inhibitory effect of fullerene in PP oxidation reactions is due to the interaction of fullerene nanoparticles with peroxy macroradicals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c0252b8b1a6cc2a52177c1cc3cced9bc https://doi.org/10.1134/s1560090413050059 Zobrazit plný text záznamu Full text from SpringerLink